A new study published by Donata Dubber of the Water Technology Research Group.
Chemical oxygen demand (COD) is widely used for wastewater monitoring, design, modelling and plant operational analysis. However this method results in the production of hazardous wastes including mercury and hexavalent chromium. The study examined the replacement of COD with total organic carbon (TOC) for general performance monitoring by comparing their relationship with influent and effluent samples from 11 wastewater treatment plants. Biochemical oxygen demand (BOD5) was also included in the comparison as a control. The results show significant linear relationships between TOC, COD and BOD5 in settled (influent) domestic and municipal wastewaters, but only between COD and TOC in treated effluents. The study concludes that TOC can be reliably used for the generic replacement of both COD (COD = 49.2 + 3.00*TOC) and BOD5 (BOD5 = 23.7 + 1.68*TOC) in influent wastewaters but only for COD (COD = 7.25 + 2.99*TOC) in final effluents.
Dubber, D. and Gray, N.F. (2010) Replacement of chemical oxygen demand (COD) with total organic carbon (TOC) for monitoring wastewater treatment performance to minimize disposal of toxic analytical waste. J. Environ. Sci. Health, Part A, 45, (12), 1595-1600.
Water Science and Water Technology are core research areas at Trinity College Dublin, Ireland. Working in the fields of wastewater treatment, water treatment and water pollution control, the Water Technology Research Group (formally Water Technology Research) has been working at the cutting edge of these core areas since 1980. This is the blog of Professor Nick Gray who heads the Water Technology Research Group based in the Centre for the Environment.
Saturday, October 23, 2010
Replacing COD with TOC
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